Electrical conductive polyaniline in various nanostructures for corrosion inhibition of carbon steel

Authors

  • Ahmed A. Al-Dulaimi MICET, Universiti Kuala Lumpur, Lot 1988, Taboh Naning 78000 Alor Gajah, Melaka, Malaysia
  • S. Hashim Department of Bioprocess and Polymer Engineering, Faculty of Chemical and energy Engineering, UTM skudai, Malaysia
  • Lway Faisal Abdulrazak Cihan research center, Computer science department, Cihan University-Sulaimaniyah, Iraq
  • M. Husham Institute of Advanced Technology (ITMA), Universiti Putra Malaysia, 43400 Serdang, Kuala lumpur, Malaysia

DOI:

https://doi.org/10.15282/jmes.12.2.2018.18.0330

Keywords:

Polyaniline; nanostructures, micelle; corrosion protection.

Abstract

Conductive polyaniline (PANI) in various nanostructures were prepared by situ polymerization for corrosion protection application of carbon steel. Anticorrosion performance of the samples was evaluated by applying salt spray and adhesion tests based on standards ASTM B117 and ASTM D3359 respectively. Synthesis of PANI in various nanostructures carried out by doping aniline monomer with phosphoric acid in four different molar ratios. Field emission scanning electron microscopy (FESEM) images confirms the variation in nanostructures of samples. The samples were also characterized using Fourier transform infrared (FTIR), X-ray diffraction (XRD), electrical conductivity and dispersion stability in ethanol medium. The transition of PANI nanostructure from nanofibers to nanorods and nanospheres occurred with the increase of molar ratios (phosphoric acid/aniline) from 0.1, 0.5, 1 and 2 respectively. The results show that coating containing PANI nanofibers has the best resistance against corrosive aggression due to the high dispersion stability and decent uniformity. Accordingly, this work finds that the morphological structure and dispersion stability for PANI has a significant impact on the anticorrosion performance.

References

Suriani M, Nik W, Mansor F, Jarkoni M, Maizurah C, Izwani I, Corrosion behavior and resistance parameters of silicon carbide nanocomposite coating on different metals. Journal of Mechanical Engineering and Sciences. 2018; 12: 3288-3301.

Nik WW, Hajar H, Suriani M, Sabri M, Ghazali M, Development of anti-corrosive paint incorporated with henna extract as a natural inhibitor. Journal of Mechanical Engineering and Sciences. 2017; 11: 3179-3188.

Hajar H, Ismail N, Zulkifli F, Sabri M, Nik W, Non-destructive tests on eco-friendly anti-corrosion paint. Journal of Mechanical Engineering and Sciences. 2017; 11: 2825- 2833.

Bhadra S, Khastgir D, Singha NK, Lee JH, Progress in preparation, processing and applications of polyaniline. Progress in Polymer Science. 2009; 34: 783-810.

Kang E, Neoh K, Tan K, Polyaniline: a polymer with many interesting intrinsic redox states. Progress in Polymer Science. 1998; 23: 277-324.

Deshpande PP, Jadhav NG, Gelling VJ, Sazou D, Conducting polymers for corrosion protection: a review. Journal of Coatings Technology and Research. 2014; 11: 473- 494.

Li Y, Zhang H, Wang X, Li J, Wang F, Growth kinetics of oxide films at the polyaniline/mild steel interface. Corrosion science. 2011; 53: 4044-4049.

Al-Dulaimi A, Hashim S, Improving The Anti-Corrosion Properties Via Surface Modification For Silicon Dioxide By Conductive Polymer. International Journal Of Mechanical And Materials Engineering (IJMME). 2012; 7: 113-118.

Tian Z, Yu H, Wang L, Saleem M, Ren F, Ren P, Chen Y, Sun R, Sun Y, Huang L, Recent progress in the preparation of polyaniline nanostructures and their applications in anticorrosive coatings. RSC Advances. 2014; 4: 28195-28208.

Shi Y, Peng L, Ding Y, Zhao Y, Yu G, Nanostructured conductive polymers for advanced energy storage. Chemical Society Reviews. 2015; 44: 6684-6696.

Guo B, Glavas L, Albertsson A-C, Biodegradable and electrically conducting polymers for biomedical applications. Progress in Polymer Science. 2013; 38: 1263- 1286.

Zhang Z, Wei Z, Zhang L, Wan M, Polyaniline nanotubes and their dendrites doped with different naphthalene sulfonic acids. Acta Materialia. 2005; 53: 1373-1379.

Fu G, Zhao J, Sun Y, Kang E, Neoh K, Conductive hollow nanospheres of polyaniline via surface-initiated atom transfer radical polymerization of 4-vinylaniline and oxidative graft copolymerization of aniline. Macromolecules. 2007; 40: 2271-2275.

Virji S, Huang J, Kaner RB, Weiller BH, Polyaniline nanofiber gas sensors: examination of response mechanisms. Nano letters. 2004; 4: 491-496.

Long Y-Z, Li M-M, Gu C, Wan M, Duvail J-L, Liu Z, Fan Z, Recent advances in synthesis, physical properties and applications of conducting polymer nanotubes and nanofibers. Progress in Polymer Science. 2011; 36: 1415-1442.

Chiou N-R, Lee LJ, Epstein AJ, Self-assembled polyaniline nanofibers/nanotubes. Chemistry of materials. 2007; 19: 3589-3591.

Ding X, Han D, Wang Z, Xu X, Niu L, Zhang Q, Micelle-assisted synthesis of polyaniline/magnetite nanorods by in situ self-assembly process. Journal of Colloid and Interface science. 2008; 320: 341-345.

Xia H, Narayanan J, Cheng D, Xiao C, Liu X, Chan HSO, Formation of ordered arrays of oriented polyaniline nanoparticle nanorods. The Journal of Physical Chemistry B. 2005; 109: 12677-12684.

Zhang D, Wang Y, Synthesis and applications of one-dimensional nano-structured polyaniline: An overview. Materials Science and Engineering: B. 2006; 134: 9-19.

Zhang Z, Wei Z, Wan M, Nanostructures of polyaniline doped with inorganic acids. Macromolecules. 2002; 35: 5937-5942.

Amarnath CA, Kim J, Kim K, Choi J, Sohn D, Nanoflakes to nanorods and nanospheres transition of selenious acid doped polyaniline. Polymer. 2008; 49: 432- 437.

Tran HD, D'Arcy JM, Wang Y, Beltramo PJ, Strong VA, Kaner RB, The oxidation of aniline to produce “polyaniline”: a process yielding many different nanoscale structures. Journal of Materials Chemistry. 2011; 21: 3534-3550.

Sathiyanarayanan S, Syed Azim S, Venkatachari G, Performance studies of phosphate‐doped polyaniline containing paint coating for corrosion protection of aluminium alloy. Journal of Applied Polymer Science. 2008; 107: 2224-2230.

Kalendová A, Veselý D, Stejskal J, Trchová M, Anticorrosion properties of inorganic pigments surface-modified with a polyaniline phosphate layer. Progress in Organic Coatings. 2008; 63: 209-221.

Al-Dulaimi AA, Hashim S, Khan M, Corrosion protection of carbon steel using polyaniline composite with inorganic pigments. Sains Malaysiana. 2011; 40: 757-763.

Vittal R, Gomathi H, Kim K-J, Beneficial role of surfactants in electrochemistry and in the modification of electrodes. Advances in colloid and interface science. 2006; 119: 55-68.

Li G, Pang S, Liu J, Wang Z, Zhang Z, Synthesis of polyaniline submicrometer-sized tubes with controllable morphology. Journal of Nanoparticle Research. 2006; 8: 1039- 1044.

Zhang L, Zhang L, Wan M, Wei Y, Polyaniline micro/nanofibers doped with saturation fatty acids. Synthetic metals. 2006; 156: 454-458.

Cao Y, Li S, Xue Z, Guo D, Spectroscopic and electrical characterization of some aniline oligomers and polyaniline. Synthetic metals. 1986; 16: 305-315.

Tang J, Jing X, Wang B, Wang F, Infrared spectra of soluble polyaniline. Synthetic metals. 1988; 24: 231-238.

Pouget J, Jozefowicz M, Epstein Aea, Tang X, MacDiarmid A, X-ray structure of polyaniline. Macromolecules. 1991; 24: 779-789.

Rana U, Chakrabarti K, Malik S, Benzene tetracarboxylic acid doped polyaniline nanostructures: morphological, spectroscopic and electrical characterization. Journal of Materials Chemistry. 2012; 22: 15665-15671.

Stejskal J, Sapurina I, Trchová M, Prokeš J, Křivka I, Tobolková E, Solid-state protonation and electrical conductivity of polyaniline. Macromolecules. 1998; 31: 2218-2222.

Al-Dulaimi AA, Wan Rosli W, Water Dispersion Conductive Polypyrrole Based on Nanocrystalline Cellulose. Advanced Materials Research. 2014; 1043: 105-108.

Al-Dulaimi AA, Wanrosli W, Preparation of Colloidal Properties and Water Dispersible Conductive Polypyrrole Nanocomposite of Nanocrystalline Cellulose. Polymers & Polymer Composites. 2016; 24: 695.

Li X, Zhuang T, Wang G, Zhao Y, Stabilizer-free conducting polyaniline nanofiber aqueous colloids and their stability. Materials Letters. 2008; 62: 1431-1434.

Chen F, Liu P, Conducting polyaniline nanoparticles and their dispersion for waterborne corrosion protection coatings. ACS applied materials & interfaces. 2011; 3: 2694-2702.

Sathiyanarayanan S, Azim SS, Venkatachari G, Preparation of polyaniline–TiO2 composite and its comparative corrosion protection performance with polyaniline. Synthetic metals. 2007; 157: 205-213.

Gonçalves G, Baldissera A, Rodrigues Jr L, Martini E, Ferreira C, Alkyd coatings containing polyanilines for corrosion protection of mild steel. Synthetic metals. 2011; 161: 313-323.

Published

2018-06-30

How to Cite

[1]
A. A. Al-Dulaimi, S. Hashim, L. F. Abdulrazak, and M. Husham, “Electrical conductive polyaniline in various nanostructures for corrosion inhibition of carbon steel”, J. Mech. Eng. Sci., vol. 12, no. 2, pp. 3738–3749, Jun. 2018.

Issue

Vol. 12 No. 2 (2018): June 2018

Section

Article

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Copyright (c) 2018 The Author(s)

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