Eggshell waste extract as potential natural corrosion inhibitor for AISI 1020 steel in acidic environment
DOI:
https://doi.org/10.15282/jmes.18.3.2024.8.0805Keywords:
Eggshell, Corrosion inhibitor, Corrosion rate, Inhibition Efficiency, AISI 1020Abstract
Using natural corrosion inhibitors from calcium carbonate has gained attention in corrosion prevention approaches as it offers comparable and significant benefits compared to other corrosion inhibitors. Consequently, eggshells with a high amount of calcium carbonate were proposed as a corrosion inhibitor to evaluate the effect on the corrosion behaviour of AISI 1020 steel. In this study, the eggshell waste was extracted in ethanol solution using a Soxhlet extractor and thickened through the rotary evaporator to produce the proposed natural corrosion inhibitor with 10%, 20%, and 30%. The characteristics of the inhibitor were then examined and verified through FTIR and XRD analysis. The corrosion performance was then evaluated through the weight loss method in 1.0 molar hydrochloric acid in different durations, which are 7, 14, and 21 days. The corrosion rate and inhibiting efficiency were also performed to analyse the effect of eggshell concentration on the AISI 1020 steel. In addition, macrostructure observations were executed to assess the physical appearances of the samples. The results show that the proposed eggshell inhibitor successfully helped improve the inhibiting efficiency of AISI 1020 steel by 88.37%. Additionally, increasing the eggshell concentration decreases the corrosion rate and increases the inhibitor efficiency. This is due to CaCO3 in eggshells, a barrier to metal surfaces. Results indicate that selecting eggshell as a natural corrosion inhibitor successfully and confirmably protected the surface. Thus, this study is a viable utilisation of sustainable use from eggshell waste in reducing the corrosion occurrence of AISI 1020 steel in an acidic environment.
References
N. Bhardwaj, P. Sharma, K. Singh, D. Rana, V. Kumar, “Phyllanthus emblica seed extract as corrosion inhibitor for stainless steel used in the petroleum industry (SS-410) in acidic medium,” Chemical Physics Impact, vol. 3, p. 100038, 2021.
N. Al-Akhras, M. Yousef, “Potential use of eucalyptus leaves as green corrosion inhibitor of steel reinforcement,” Journal of Building Engineering, vol. 35, p. 101848, 2020.
G. Lei, T. Bochuan, L. Wenpo, L. Qingbiao, Z. Xingwen, O. Ime Bassey, “Banana leaves water extracts as inhibitor for X70 steel corrosion in HCl medium,” Journal of Molecular Liquids, vol. 327, p. 114828, 2020.
M. Khayatkashani et al., “Insight into the corrosion inhibition of Biebersteinia multifida root extract for carbon steel in acidic medium,” Science of The Total Environment, vol. 836, p. 155527, 2022.
H. Rajesh, P. Dwarika, B. Indra, D. Omar, B. Avni, “Evaluation of Gloriosa superba seeds extract as corrosion inhibition for low carbon steel in sulfuric acidic medium: A combined experimental and computational studies,” Journal of Molecular Liquids, vol. 323, p. 114958, 2020.
Y. Fernine, E. Ech-chihbi, N. Arrousse, F. El Hajjaji, F. Bousraf, M. Ebn Touhami, et al., “Ocimum basilicium seeds extract as an environmentally friendly antioxidant and corrosion inhibitor for aluminium alloy 2024 -T3 corrosion in 3 wt% NaCl medium,” Colloids and Surface A: Physicochemical and Engineering Aspects, vol. 627, p. 127232, 2021.
A. Said, C. Driss, Z. Meryem, R. Malak, L. Zouhair, H. Najat, “Ceratonia Siliqua L seeds extract as eco-friendly corrosion inhibitor for carbon steel in 1 M HCl: Characterization, electrochemical, surface analysis, and theoretical studies,” Journal of Molecular Structure, vol. 1240, p. 130611, 2021.
R. Haldhar, D. Prasad, N. Mandal, F. Benhiba, I. Bahadur, O. Dagdag, “Anticorrosive properties of a green and sustainable inhibitor from leaves extract of Cannabis sativa plant: Experimental and theoretical approach,” Colloids and Surface A: Physicochemical and Engineering Aspects, vol. 614, p. 126211, 2021.
J. Kaur, A. Saxena, V. P. Reddy, D. Sathiaraj, M. Agrawal, K. K. Saxena, “Lepidium Didymium plant extract as eco-friendly corrosion inhibitor for steel in acidic medium,” Indian Journal of Engineering and Materials Sciences, vol. 30, no. 2, pp. 256–264, 2023.
A. S. Fouda, A. Y. El-Etre, M. Mahmoud, “Plant Doum (Hyphaenethebaica L.) as a safe corrosion inhibitor for carbon steel in a solution of HCl,” International Journal of Corrosion and Scale Inhibition, vol. 10, no. 4, pp. 1547–1565, 2021.
F. A. Ansari, Sudheer, D. S. Chauhan, M. A. Quraishi, “Oleochemicals as corrosion inhibitors,” in Organic Corrosion Inhibitors: Synthesis, Characterization, Mechanism, and Applications, pp. 343–369, 2021.
L. Qi-feng, Q. Wei, X. Wen, R. Yan-Jie, C. Jian, Y. Mao-hai, et al., “Comparative study of CaO and CaCO3 on microstructure refinement, mechanical and corrosion resistance of AM60 alloy,” Journal of Materials Research and Technology, vol. 30, pp. 307–317, 2024.
M. S. Tizo, L. A. V. Blanco, A. C. Q. Cagas, B. R. B. Dela Cruz, J. C. Encoy, J. V. Gunting, et al., “Efficiency of calcium carbonate from eggshells as an adsorbent for cadmium removal in aqueous solution,” Sustainable Environment Research, vol. 28, no. 6, pp. 326–332, 2018.
M. F. Nassar, T. Z. Taban, R. F. Obaid, M. H. Shadhar, H. A. Almashhadani, M. M. Kadhim, et al., “Study to amino acid-based inhibitors as an effective anti-corrosion material,” Journal of Molecular Liquids, vol. 360, p. 119449, 2022.
M. Oubaaqa, M. Ouakki, M. Rbaa, A. S. Abousalem, M. Maatallah, F. Benhiba, et al., “Insight into the corrosion inhibition of new amino-acids as efficient inhibitors for mild steel in HCl solution: Experimental studies and theoretical calculations,” Journal of Molecular Liquid,s vol. 334, p. 116520, 2021.
C. E. Byrne, O. D’Alessandro, C. Deyá, “Tara Tannins as a green sustainable corrosion inhibitor for aluminum,” Journal of Material Engineering Performance, vol. 31, no. 4, pp. 2918–2933, 2022.
C. Merimi, B. Hammouti, K. Zaidi, B. Hafez, H. Elmsellem, R. Touzani, et al., “Acetylsalicylic acid as an environmentally friendly corrosion inhibitor for carbon steel XC48 in chloride environment,” Journal of Molecular Structure, vol. 1278, p. 134883, 2023.
F. Gapsari, H. Wijaya, R. Septiari, Andoko, “Evaluation of bee wax propolis inhibitor for corrosion protection on stainless steel in various pH solution,” Case Studies in Chemical and Environmental Engineering, vol. 6, p. 100227, 2022.
A. A. Ayoola, R. Babalola, B. M. Durodola, E. E. Alagbe, O. Agboola, E. O. Adegbile, “Corrosion inhibition of A36 mild steel in 0.5 M acid medium using waste citrus limonum peels,” Results in Engineering, vol. 15, p. 100490, 2022.
P. Du, S. Deng, X. Li, “Mikania micrantha extract as a novel inhibitor for the corrosion of cold rolled steel in Cl2HCCOOH solution,” Journal of Materials Research and Technology, vol. 19, pp. 2526–2545, 2022.
M. A. Deyab, Q. Mohsen, L. Guo, “Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte,” Scientific Reports, vol. 12, no. 1, pp. 1–14, 2022.
N. Hossain, M. A. Chowdhury, M. Rana, M. Hassan, S. Islam, “Terminalia arjuna leaves extract as green corrosion inhibitor for mild steel in HCl solution,” Results in Engineering, vol. 14, p. 100438, 2022.
X. Sun, Y. Qiang, B. Hou, H. Zhu, H. Tian, “Cabbage extract as an eco-friendly corrosion inhibitor for X70 steel in hydrochloric acid medium,” Journal of Molecular Liquids, vol. 362, p. 119733, 2022.
V. Vorobyova, M. Skiba, K. Andrey, “Tomato pomace extract as a novel corrosion inhibitor for the steel in industrial media: The role of chemical transformation of the extract and proinhibition effect,” Journal of Molecular Structure, vol. 1264, p. 133155, 2022.
A. J. Mwakalesi, “Corrosion inhibition of mild steel in sulphuric acid solution with Tetradenia riparia leaves aqueous extract: kinetics and thermodynamics,” Biointerface Research in Applied Chemistry, vol. 13, no. 1, pp. 1-13, 2023.
S. S. A. Nikitasari, G. Priyotomo, A. Royani, “Exploration of Eucheuma Seaweed Algae extract as a novel green corrosion inhibitor for API 5L carbon steel in hydrochloric acid medium,” International Journal of Engineering, vol. 35, no. 6, pp. 1209–1216, 2022.
R. Ihamdane, M. Ouakki, M. Galai, E. Ech-chihbi, M. Tiskar, M. E. Touhami, et al., “The inhibition effect of aerial part of Daucus carota L essential oil on the corrosion performance of mild steel in HCl medium,” Biointerface Research in Applied Chemistry, vol. 12, no. 5, pp. 6487–6503, 2022.
M. Afrokh, S. Baroud, Y. Kerroum, A. Hatimi, S. Tahrouch, I. Sadki, et al., “Green approach to corrosion inhibition of carbon steel by fucus spiralis extract in 1 M HCl medium,” Biointerface Research in Applied Chemistry, vol. 12, no. 5, pp. 7075–7091, 2022.
R. Rajalakshmi, S. Subhashini, S. Leelavathi, R. Geethanjali, “Study of the inhibitive action of bakery waste for corrosion of mild steel in acid medium,” Journal of Nepal Chemical Society, vol. 25, pp. 29–36, 2010.
M. F. Montemor, “Functional and smart coatings for corrosion protection: A review of recent advances,” Surface and Coatings Technology, vol. 258, pp. 17-37, 2014.
D. Snihirova, S. V. Lamaka, M. F. Montemor, “‘SMART’ protective ability of water-based epoxy coatings loaded with CaCO3 microbeads impregnated with corrosion inhibitors applied on AA2024 substrates,” Electrochimica Acta, vol. 83, pp. 439–447, 2012.
R. Raj, Y. Morozov, L. M. Calado, M. G. Taryba, R. Kahraman, R. A. Shakoor, et al., “Calcium carbonate particles loaded with triethanolamine and polyethylenimine for enhanced corrosion protection of epoxy coated steel,” Corrosion Science, vol. 167, p. 108548, 2020.
G. R. Osorio-Celestino, M. Hernandez, D. Solis-Ibarra, S. Tehuacanero-Cuapa, A. Rodríguez-Gómez, A. P. Gómora-Figueroa, “Influence of calcium scaling on corrosion behavior of steel and aluminum alloys,” ACS Omega, vol. 5, no. 28, pp. 17304–17313, 2020.
T. A. Abu Bakar, M. F. Rosly, N. S. A. Mohamad Jafar, “Eggshell coated grey cast iron for corrosion applications,” Jurnal Teknologi, vol. 79, no. 7–4, pp. 1-6, 2017.
W. Liu, J. Li, X. Huang, J. Bi, “Corrosion protection of Q235 steel using epoxy coatings loaded with calcium carbonate microparticles modified by sodium lignosulfonate in simulated concrete pore solutions,” Materials, vol. 14, no. 8, p. 1982, 2021.
C. Arunlertaree, W. Kaewsomboon, A. Kumsopa, P. Pokethitiyook, P. Panyawathanakit, “Removal of lead from battery manufacturing wastewater by eggshell,” Songklanakarin Journal of Science and Technology, vol. 29, no. 3, p. 857868, 2007.
N. M. Jafar, T. Abubakar, C. Y. Chong, N. H. Ahmad, “Effect of sintering temperature on the morphology and adhesion strength of eggshell coating on mild steel,” Solid State Phenomena, vol. 264, pp. 190–193, 2017.
O. Sanni, A. P. I. Popoola, O. S. I. Fayomi, “The inhibitive study of eggshell powder on uns n08904 austenitic stainless-steel corrosion in chloride solution,” Defence Technology, vol. 14, no. 5, pp. 463–468, 2018.
M. Alagawany, S. S. Elnesr, M. R. Farag, R. Tiwari, M. I. Yatoo, K. Karthik. et al., “Nutritional significance of amino acids, vitamins and minerals as nutraceuticals in poultry production and health – A comprehensive review,” Veterinary Quarterly, vol. 41, no. 1, pp. 1–29, 2021.
O. Sanni, S. A. Iwarere, M. O. Daramola, “Investigation of eggshell agro-industrial waste as a potential corrosion inhibitor for mild steel in oil and gas industry,” Sustainability, vol. 15, no. 7, p. 6155, 2023.
C. Horn, “Soxhlet extraction method EPA 3540C”, Caltest Standard Operating Procedure, pp. 1-11, 2009.
N. Mohan, R. Palangadan, F. B. Fernandez, H. Varma, “Preparation of hydroxyapatite porous scaffold from a ‘coral-like’ synthetic inorganic precursor for use as a bone substitute and a drug delivery vehicle,” Materials Science and Engineering C, vol. 92, pp. 329–337, 2018.
ASTM Standard G1-03, “Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens,” American Society for Testing and Materials, United States, 2017.
S. Abdulfatai, N. Okon Eddy, I. Sulaiman, A. Muhammad, “FTIR spectroscopic information on the corrosion inhibitor potentials of ampicillin in HCl solution.” Innovative Science and Engineering, vol 2, pp. 41-48, 2012
R. S. Putra, A. Liyanita, N. Arifah, E. Puspitasari, Sawaludin, M. N. Hizam, “Enhanced electro-catalytic process on the synthesis of FAME using CaO from eggshell,” Energy Procedia, vol. 105, pp. 289–296, 2017.
R. Raj, Y. Morozov, L. M. Calado, M. G. Taryba, R. Kahraman, A. Shakoor, et al., “Inhibitor loaded calcium carbonate microparticles for corrosion protection of epoxy-coated carbon steel,” Electrochimica Acta, vol. 319, pp. 801–812, 2019.
W. M. I. Wan Mohamad Kamaruzzaman, M. S. Shaifudin, N. A. Mohd Nasir, N. A. S. Mohd Hamidi, N. Yusof, A. Adnan, et al., “Eggshells biowaste filler for improving the anticorrosive behaviour of waterborne polyurethane coatings on mild steel in artificial seawater,” Journal of Materials Research and Technology, vol. 21, pp. 3815–3827, 2022.
K. Pandian, S. Vivekananthan, D. J. Thiruvadigal, S. Sagadevan, “Natural green inhibitors-versatile materials for corrosion inhibition of steel structures,” Innovations in Corrosion and Materials Science, vol. 7, no. 2, 2018.
Y. P. Yee, S. N. Saud, E. Hamzah, “Pomelo Peel extract as corrosion inhibitor for steel in simulated seawater and acidic mediums,” Journal of Material Engineering and Performance, vol. 29, no. 4, pp. 2202–2215, 2020.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 The Author(s)
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
