Effect of solution treatment on the microstructure and mechanical properties of Ti-6Al-6Mo hot-rolled alloy

Authors

  • Alfirano . Department of Metallurgical Engineering, University of Sultan Ageng Tirtayasa, Jl. Jenderal Sudirman KM 3 Cilegon 42435, Indonesia Phone: +62254376712; Fax: +62254376712
  • S. S. Friandani Department of Metallurgical Engineering, University of Sultan Ageng Tirtayasa, Jl. Jenderal Sudirman KM 3 Cilegon 42435, Indonesia Phone: +62254376712; Fax: +62254376712
  • C. Sutowo Indonesian Institute of Sciences-LIPI, Jl. Raya Puspitek, Tangerang Selatan 15413, Indonesia

DOI:

https://doi.org/10.15282/jmes.13.2.2019.07.0404

Keywords:

elastic modulus, solution treatment, hot rolling,  Ti-6Al-6Mo

Abstract

Titanium and its alloys are widely used in biomedical applications due to their unique combination of good hot workability, high specific strength and good corrosion resistance. In this study, elastic modulus, hardness and the effects of solution treatment on microstructures and mechanical properties of Ti-6Al-6Mo hot-treated alloy were investigated using OM (optical microscopy), XRD (X-ray diffractometry), SEM (Scanning electron microscopy), Ultrasonic testing and hardness testing. Previously, the sampels were hot-rolled at 900oC for 1 h with a total reduction of 50%,and then followed by air cooling. The samples were carried out solution treatment for 1 h at 850oC and 950oC, followed by water cooling and at temperature of 1050oC with water and air cooling. The results indicate that the hardness of the Ti-6Al-6Mo alloy increased with the increasing of solution treatment temperature on the water cooling, while the elastic modulus was decreased. The lowest elasticity modulus value and the highest hardness, 125.4 GPa and 46.3 RC were obtained at 1050oC with equiaxed micro structure and β' precipitate. XRD analysis exhibited the presence of α and β phases in Ti-6Al-6Mo alloys after solution treatment. Based on the relative intensity of XRD strongest peak analysis, the α phase intensity decreases with the increasing of solution treatment temperature, this phenomenon causes the decreasing of elasticity modulus value with the increasing of solution treatment temperature on water cooling medium.

References

Niinomi M. Metallic biomaterials. Journal of Artificial Organs. 2008;11:105-10.

Khan MAR, Rahman MM, Kadirgama K, Noor MM. Prediction of surface roughness of Ti-6Al-4V in electrical discharge machining: a regression model. Journal of Mechanical Engineering and Sciences. 2011;1:16-24.

Zhang Q, Chen J, Tan H, Lin X, Huang W. Microstructure evolution and mechanical properties of laser additive manufactured Ti–5Al–2Sn–2Zr–4Mo–4Cr alloy. Transactions of Nonferrous Metals Society of China. 2016;26:2058-66.

Hamdan SH, Said AYM, Biki JR. Surface finish when threading titanium-based alloy under dry machining. Journal of Mechanical Engineering and Sciences. 2014;7:1062-69.

Ren H, Tian X, Liu D, Liu J, Wang H. Microstructural evolution and mechanical properties of laser melting deposited Ti–6.5Al–3.5Mo–1.5Zr–0.3Si titanium alloy. Transactions of Nonferrous Metals Society of China. 2015;25:1856-64.

Li G, Li J, Tian X, Cheng X, Bei H, Wang H. Microstructure and properties of a novel titanium alloy Ti-6Al-2V-1.5Mo-0.5Zr-0.3Si manufactured by laser additive manufacturing. Materials Science and Engineering: A. 2017;684:233-38.

Zhang Q, Chen J, Zhao Z, Tan H, Xin L, Huang W. Microstructure and anisotropic tensile behavior of laser additive manufactured TC21 titanium alloy. Materials Science and Engineering: A. 2016;673:204-12.

O'Brien B, Stinson J, Carroll W. Initial exploration of Ti–Ta, Ti–Ta–Ir and Ti–Ir alloys: Candidate materials for coronary stents. Acta Biomaterialia. 2008;4:1553-59.

Cho K, Niinomi M, Nakai M, Hieda J, Kawasaki Y. Development of high modulus TiFeCu alloys for biomedical applications. Material Transactions. 2013;54:574-81.

Alfirano, Mineta S, Namba S, Yoneda T, Ueda K, Narushima T. Heat treatment of ASTM F75 Co-Cr-Mo-C-Si-Mn alloys. Materials Science Forum. 2010;654-656,2180-83.

Mad Rosip NI, Ahmad S, Jamaludin KR, Noor FM. Production of 316L stainless steel (SS316L) foam via slurry method. Journal of Mechanical Engineering and Sciences. 2013;5:707-12.

Gil Mur FX, Rodríguez D, Planell JA. Influence of tempering temperature and time on the α’-Ti-6Al-4V martensite. Journal of Alloys and Compounds. 1996;234:287-89.

Wanying L, Yuanhua L, Yuhai C, Taihe S, Singh A. Effect of different heat treatments on microstructure and mechanical properties of Ti6Al4V titanium alloy. Rare Metal Materials and Engineering. 2017;46:634-39.

Venkatesh BD, Chen DL, Bhole SD. Effect of heat treatment on mechanical properties of Ti–6Al–4V ELI alloy. Materials Science and Engineering A. 2009;506:117-24.

Kumar C, Das M, Paul CP, Bindra KS. Characteristics of fiber laser weldments of two phases (α+ β) titanium alloy. Journal of Manufacturing Processes. 2018;35:351-59.

Niinomi M. Mechanical properties of biomedical titanium alloys. Materials Science and Engineering: A. 1998;243:231-36.

Kuroda D, Niinomi M, Morinaga M, Kato Y, Yashiro T. Design and mechanical properties of new β type titanium alloys for implant materials. Materials Science and Engineering: A. 1998;243:244-49.

Thoemmes A, Ivanov IV, Kashimbetova AA. Comparison of mechanical properties and microstructure of annealed and quenched Ti-Nb alloys. Key Engineering Materials. 2018;769:29-34.

Kawahara H. Cytotoxicity of implantable metals and alloys. Bulletin of the Japan Institute of Metals. 1992;31:1033-39.

Kim S, Jung H, Rim HJ, Lee HS, Lee W. Fabrication of reinforced α+β titanium alloys by infiltration of Al into porous Ti-V compacts. Journal of Alloys and Compounds. 2018;768:775-81.

Wang J, Qin Z, Xiong F, Wang S, Lu X, Li C. Design and preparation of low-cost α + β titanium alloy based on assessment of Ti-Al-Fe-Cr system. Materials Science and Engineering: A. 2018;73:63-69.

Jiang B, Emura S, Tsuchiya K. Microstructural evolution and its effect on the mechanical behavior of Ti-5Al-5Mo-5V-3Cr alloy during aging. Materials Science and Engineering: A. 2018;731:239-48.

Widu F, Drescher D, Junker R, Bourauel C. Corrosion and biocompatibility of orthodontic wires. Journal of Materials Science Materials in Medicine. 1999;10:275-81.

Shi Y, Zhang G, Li M, Guo D, Zhang Z, Wei B, Li J, Zhang X. Effect of heat treatment on the microstructure and tensile properties of deformed α/β Ti–47Zr–5Al–3V alloy. Journal of Alloys and Compounds. 2016;665:1-6.

Ji X, Emura S, Liu T, Suzuta K, Min X, Tsuchiya K. Effect of oxygen addition on microstructures and mechanical properties of Ti-7.5 Mo alloy. Journal of Alloys and Compounds. 2018;737:221-29.

Schmoelzer T, Mayer S, Haupt F, Zickler GA, Sailer C, Lottermoser L, Güther V, Liss KD, Clemens H. Phase transition and ordering temperatures of TiAl-Mo alloys investigated by in-situ diffraction experiments. Materials Science Forum. 2010;654-656:456.

Lu Y, Yamada J, Nakamura J, Yoshimi K, Kato H. Effect of B2-ordered phase on the deformation behavior of Ti-Mo-Al alloys at elevated temperature. Journal of Alloys and Compounds. 2017;696: 130-35.

Wei Z, Peng G, Yongqing Z, Shewei X, Qian L, Jun C, Shiyuan Z, Chaowen H. Evolution of primary α phase morphology and mechanical properties of a novel high-strength titanium alloy during heat treatment. Rare Metal Materials and Engineering. 2017;46:2852-56.

Davari D, Rostami Abbasi SM. Effects of annealing temperature and quenching medium on microstructure, mechanical properties as well as fatigue behavior of Ti-6Al-4V alloy. Materials Science and Engineering: A. 2017;683:1-8.

Galarraga H, Warren RJ, DA Lados, Dehoff RR, Kirk MM, Nandwan P. Effects of heat treatments on microstructure and properties of Ti-6Al-4V ELI alloy fabricated by electron beam melting (EBM). Materials Science and Engineering: A. 2017;685:417-28.

Zhao C, Zhang X, Cao P. Mechanical and electrochemical characterization of Ti–12Mo–5Zr alloy for biomedical application. Journal of Alloys and Compounds. 2011;509:8235-38.

Mohammed MT, Khan ZA, Siddiquee AN. Beta titanium alloys: The lowest elastic modulus for biomedical applications: A review. International Journal of Chemical, Molecular, Nuclear, Materials and Metallurgical Engineering. 2014;8:788-93.

Li CL, Ye WJ, Mi XJ, Hui SX, Lee DG, Lee YT. Development of low cost and low elastic modulus of Ti-Al-Mo-Fe alloys for automotive applications. Key Engineering Materials. 2013;551:114-17.

Borradaile JB, Jeal RH. Mechanical properties of titanium alloys. Warrendale: Metallurgical society of AIME. 1980;141:1-3.

Patil S, Kekade S, Phapale K, Jadhav S, Powar A, Supare A, Singh R. Effect of α and β phase volume fraction on machining characteristics of titanium alloy Ti6Al4V. Procedia Manufacturing. 2016;6:63-70.

Turichin GA, Klimova-Korsmik OG, Gushchina MO, Shalnova SA, Korsmik RS, Cheverikin VV, Tataru AS. Features of structure formation in α+β titanium alloys. Procedia CIRP. 2018;74:188-91.

Mineta S, Alfirano, Namba S, Yoneda T, Ueda K, Narushima T. Phase and morphology of carbides in ASTM F75 Co-Cr-Mo-C alloys formed at 1473 to 1623 K. Materials Science Forum. 2010;654-656,2176-79.

Jiang B, Emura S, Tsuchiya K. Microstructural evolution and its effect on the mechanical behavior of Ti-5Al-5Mo-5V-3Cr alloy during aging. Materials Science Engineering A. 2018;731:239-48.

Yilmazer H, Niinomi M, Cho K, Nakai M, Hieda J, Sato S, Todaka Y. Microstructural evolution of precipitation-hardened β-type titanium alloy through high-pressure torsion. Acta Materialia. 2014;80:172-182.

Abdulsalam KS, Alzubaydi TL, Ajeel SA. Influence of heat treatment conditions on microstructure of Ti- 6Al-7Nb alloy as used surgical implant materials. Engineering and Technology Journal. 2007;25:431-442.

Foul A, Aranas Jr. C, Guo B, Jonas JJ. Dynamic transformation of alpha to beta at temperatures below the beta-transus. Materials Science and Engineering: A. 2018;722:156-59.

Majumdar P, Singh SB, Chakraborty M. Elastic modulus of biomedical titanium alloys by nano-indentation and ultrasonic techniques – A comparative study. Materials Science and Engineering A. 2008;489:419-25.

Lütjering G, Williams JC. Titanium. Springer. 2003.

Ho WF, Ju CP, Lin JHC. Structure and properties of cast binary Ti-Mo alloys. Biomaterials. 1999;20:2115-22.

Mantri SA, Choudhuri D, Alam T, Viswanathan GB, Sosa JM, Fraser HL, Banerjee R. Tuning the scale of α precipitates in β-titanium alloys for achieving high strength. Scripta Materialia. 2018;154, 139-44.

Ji Z, Chen Y, Qiang Y, Shen C, Li H. Effect of deformation of constituent phases on mechanical properties of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si titanium alloy. Materials Science and Engineering: A. 2018;723:29-37.

Lai MJ, Li T, Raabe D. ω phase acts as a switch between dislocation channeling and joint twinning- and transformation-induced plasticity in a metastable β titanium alloy. Acta Materialia. 2018;151:67-77.

Hon YH, Wang JY, Pan YN. Composition/phase structure properties of titanium-niobium alloys. Materials Transaction. 2003;44:2384-90.

Hao YL, Niinomi M, Kuroda D, Fukunaga F, Zhou YL, Yang R, Suzuki A. Young's modulus and mechanical properties of Ti-29Nb-13Ta-4.6Zr in relation to α” martensite. Metallurgical and Materials Transactions A. 2002;33:3137-44.

Banerjee R, Nag S, Fraser HL. A novel combinatorial approach to the development of beta titanium alloys for orthopedic implants. Materials Science and Engineering: C. 2005;25:282-89.

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Published

2019-06-28

How to Cite

[1]
A. ., S. S. Friandani, and C. Sutowo, “Effect of solution treatment on the microstructure and mechanical properties of Ti-6Al-6Mo hot-rolled alloy”, J. Mech. Eng. Sci., vol. 13, no. 2, pp. 4857–4868, Jun. 2019.

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