Morphological changes of ZnO nanostructures upon addition of Trisodium Citrate (Na3C6H5O7) at different reaction temperatures

Authors

  • Aqilah Kamaruzaman Innovative Manufacturing, Mechatronics, Sports (Imams) Lab, Faculty of Manufacturing Mechatronics Engineering Technology, Universiti Malaysia Pahang, 26600, Pekan, Pahang, Malaysia
  • Nurul Akmal Che Lah Innovative Manufacturing, Mechatronics, Sports (Imams) Lab, Faculty of Manufacturing Mechatronics Engineering Technology, Universiti Malaysia Pahang, 26600, Pekan, Pahang, Malaysia

DOI:

https://doi.org/10.15282/jmmst.v5i1.5891

Keywords:

Zinc Oxide, nanotechnology, Trisodium Citrate, Hydrothermal Method, TEM

Abstract

Due to its interesting physical and chemical properties, zinc oxide (ZnO) is considered one of the front runners of numerous metal oxide semiconductors. In this paper, ZnO nanostructure are synthesised by hydrothermal method with trisodium citrate (TC) as the emulsfying agent. The mean diameetr of ZnO nanostructure are observed with increment of reaction temperature. The mean size results into no change to mean diameter upon increment of reaction temperature but the cumulative frequencies of size distribution showing ZnO nanostructure synthesised in higher temperature to have narrower size distribution. The addition of TC also results into much smaller ZnO nanostructure with mean diameter 8nm

References

T. G. Smijs and S. Pavel, "Titanium dioxide and zinc oxide nanoparticles in sunscreens: focus on their safety and effectiveness," Nanotechnology, science and applications, vol. 4, pp. 95-112, 2011.

J. A. Ruszkiewicz, A. Pinkas, B. Ferrer, T. V. Peres, A. Tsatsakis, and M. Aschner, "Neurotoxic effect of active ingredients in sunscreen products, a contemporary review," Toxicology Reports, vol. 4, pp. 245-259, 2017/01/01/ 2017.

P. Chaudhary, P. Singh, and V. Kumar, "Synthesis and characterization of pure ZnO and La-doped ZnO (Zn0.98La0.02O) films via novel sol-gel screen- printing method," Optik, vol. 158, pp. 376-381, 2018/04/01/ 2018.

J.-Q. Wen, J.-M. Zhang, and Z.-Q. Li, "Structural and electronic properties of Y doped ZnO with different Y concentration," Optik, vol. 156, pp. 297-302, 2018/03/01/ 2018.

F.-X. Xiao, S.-F. Hung, H. B. Tao, J. Miao, H. B. Yang, and B. Liu, "Spatially branched hierarchical ZnO nanorod-TiO2 nanotube array heterostructures for versatile photocatalytic and photoelectrocatalytic applications: towards intimate integration of 1D–1D hybrid nanostructures," Nanoscale, vol. 6, pp. 14950-14961, 2014.

P. J. P. Espitia, N. d. F. F. Soares, J. S. d. R. Coimbra, N. J. de Andrade, R. S. Cruz, and E. A. A. Medeiros, "Zinc Oxide Nanoparticles: Synthesis, Antimicrobial Activity and Food Packaging Applications," Food and Bioprocess Technology, vol. 5, pp. 1447-1464, 2012.

L. He, Y. Liu, A. Mustapha, and M. Lin, "Antifungal activity of zinc oxide nanoparticles against Botrytis cinerea and Penicillium expansum," Microbiol Res, vol. 166, pp. 207-15, Mar 20 2011.

N. Jones, B. Ray, K. T. Ranjit, and A. C. Manna, "Antibacterial activity of ZnO nanoparticle suspensions on a broad spectrum of microorganisms," FEMS Microbiol Lett, vol. 279, pp. 71-6, Feb 2008.

A. Sirelkhatim, S. Mahmud, A. Seeni, N. H. M. Kaus, L. C. Ann, S. K. M. Bakhori, et al., "Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism," Nanomicro Lett, vol. 7, pp. 219-242, 2015.

Z. L. Wang, "ZnO Nanostructure " 2004.

J.-C. Chen and C.-T. Tang, "Preparation and application of granular ZnO/Al2O3 catalyst for the removal of hazardous trichloroethylene," Journal of Hazardous Materials, vol. 142, pp. 88-96, 2007/04/02/ 2007.

P. Basnet, T. Inakhunbi Chanu, D. Samanta, and S. Chatterjee, "A review on bio-synthesized zinc oxide nanoparticles using plant extracts as reductants and stabilizing agents," Journal of Photochemistry and Photobiology B: Biology, vol. 183, pp. 201-221, 2018/06/01/ 2018.

M. Joulaei, K. Hedayati, and D. Ghanbari, "Investigation of magnetic, mechanical and flame retardant properties of polymeric nanocomposites: Green synthesis of MgFe2O4 by lime and orange extracts," Composites Part B: Engineering, vol. 176, p. 107345, 2019/11/01/ 2019.

P. Mahajan, A. Sharma, B. Kaur, N. Goyal, and S. Gautam, "Green synthesized (Ocimum sanctum and Allium sativum) Ag-doped cobalt ferrite nanoparticles for antibacterial application," Vacuum, vol. 161, pp. 389-397, 2019/03/01/ 2019.

K. C. Suresh, S. Surendhiran, P. Manoj Kumar, E. Ranjth Kumar, Y. A. S. Khadar, and A. Balamurugan, "Green synthesis of SnO2 nanoparticles using Delonix elata leaf extract: Evaluation of its structural, optical, morphological and photocatalytic properties," SN Applied Sciences, vol. 2, p. 1735, 2020/09/25 2020.

A. E. D. Mahmoud, "Nanomaterials: Green Synthesis for Water Applications," in Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications, O. V. Kharissova, L. M. T. Martínez, and B. I. Kharisov, Eds., ed Cham: Springer International Publishing, 2020, pp. 1-21.

T. Ahmad, "Reviewing the Tannic Acid Mediated Synthesis of Metal Nanoparticles," Journal of Nanotechnology, vol. 2014, pp. 1-11, 2014.

A. Krol, P. Pomastowski, K. Rafinska, V. Railean-Plugaru, and B. Buszewski, "Zinc oxide nanoparticles: Synthesis, antiseptic activity and toxicity mechanism," Adv Colloid Interface Sci, vol. 249, pp. 37-52, Nov 2017.

N. Padmavathy and R. Vijayaraghavan, "Enhanced bioactivity of ZnO nanoparticles-an antimicrobial study," Sci Technol Adv Mater, vol. 9, p. 035004, Jul 2008.

R. Wahab, S. G. Ansari, Y. S. Kim, H. K. Seo, G. S. Kim, G. Khang, et al., "Low temperature solution synthesis and characterization of ZnO nano-flowers," Materials Research Bulletin, vol. 42, pp. 1640-1648, 2007.

L. Ge, X. Jing, J. Wang, J. Wang, S. Jamil, Q. Liu, et al., "Trisodium citrate assisted synthesis of ZnO hollow spheres via a facile precipitation route and their application as gas sensor," Journal of Materials Chemistry, vol. 21, pp. 10750-10754, 2011.

Y. Bao, C. Wang, and J. Ma, "Trisodium citrate as bridging and suppressing agent to control synthesis of ZnO hollow hierarchical microspheres and their photocatalytic properties," Ceramics International, vol. 42, pp. 1746-1755, 2016/01/01/ 2016.

S. Baruah and J. Dutta, "Hydrothermal growth of ZnO nanostructures," Science and Technology of Advanced Materials, vol. 10, p. 013001, 2009/01/01 2009.

Y.-k. Qin, X.-p. Guo, F.-y. Tou, H. Pan, J.-n. Feng, J. Xu, et al., "Cytotoxicity of TiO2 nanoparticles toward Escherichia coli in an aquatic environment: effects of nanoparticle structural oxygen deficiency and aqueous salinity," Environmental Science: Nano, vol. 4, pp. 1178-1188, 2017.

Y.-y. She, J. Yang, and K.-q. Qiu, "Synthesis of ZnS nanoparticles by solid-liquid chemical reaction with ZnO and Na2S under ultrasonic," Transactions of Nonferrous Metals Society of China, vol. 20, pp. s211-s215, 2010/05/01/ 2010.

A. K. Thottoli and A. K. A. Unni, "Effect of trisodium citrate concentration on the particle growth of ZnS nanoparticles," Journal of Nanostructure in Chemistry, vol. 3, p. 56, 2013/07/15 2013.

S. Suwanboon, P. Amornpitoksuk, and C. Randorn, "Effect of tartaric acid as a structure-directing agent on different ZnO morphologies and their physical and photocatalytic properties," Ceramics International, vol. 45, pp. 2111-2116, 2019/02/01/ 2019.

Y. Bao, C. Wang, and J.-z. Ma, "Morphology control of ZnO microstructures by varying hexamethylenetetramine and trisodium citrate concentration and their photocatalytic activity," Materials & Design, vol. 101, pp. 7-15, 2016/07/05/ 2016.

H. Huang, H. d. Toit, M. O. Besenhard, S. Ben-Jaber, P. Dobson, I. Parkin, et al., "Continuous flow synthesis of ultrasmall gold nanoparticles in a microreactor using trisodium citrate and their SERS performance," Chemical Engineering Science, vol. 189, pp. 422-430, 2018/11/02/ 2018.

J.-W. Park and J. S. Shumaker-Parry, "Structural Study of Citrate Layers on Gold Nanoparticles: Role of Intermolecular Interactions in Stabilizing Nanoparticles," Journal of the American Chemical Society, vol. 136, pp. 1907-1921, 2014/02/05 2014.

Downloads

Published

19-02-2021

How to Cite

Kamaruzaman, A., & Che Lah, N. A. (2021). Morphological changes of ZnO nanostructures upon addition of Trisodium Citrate (Na3C6H5O7) at different reaction temperatures. Journal of Modern Manufacturing Systems and Technology, 5(1), 18–22. https://doi.org/10.15282/jmmst.v5i1.5891

Issue

Section

Articles

Similar Articles

<< < 1 2 3 4 5 6 > >> 

You may also start an advanced similarity search for this article.